Stabilizing γ‐MgH <sub>2</sub> at Nanotwins in Mechanically Constrained Nanoparticles
نویسندگان
چکیده
Reversible hydrogen uptake and the metal/dielectric transition make Mg/MgH2 system a prime candidate for solid-state storage dynamic plasmonics. However, high dehydrogenation temperatures slow hamper broad applicability. One promising strategy to improve is formation of metastable γ-MgH2. A nanoparticle (NP) design, where γ-MgH2 forms intrinsically during hydrogenation presented mechanism based on transmission electron microscopy results proposed. Volume expansion causes compressive stress within confined, anisotropic NPs, leading plastic deformation β-MgH2 via (301)β twinning. It proposed that these twins nucleate nanolamellas, which are stabilized by residual stress. Understanding this crucial step toward cycle-stable, Mg-based plasmonic hydrogen-storage materials with improved dehydrogenation. envisioned more general design confined NPs utilizes inherent volume reform each rehydrogenation.
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ژورنال
عنوان ژورنال: Advanced Materials
سال: 2021
ISSN: ['1521-4095', '0935-9648']
DOI: https://doi.org/10.1002/adma.202008259